解:
$\begin{aligned}&\left(-\frac{a^{2}}{b}\right)^{2}\cdot\left(-\frac{b^{2}}{a}\right)^{3}\div\left(-\frac{b}{a}\right)\\=&\frac{a^{4}}{b^{2}}\cdot\left(-\frac{b^{6}}{a^{3}}\right)\cdot\left(-\frac{a}{b}\right)\\=&a^{4 - 3+1}b^{-2 + 6-1}\\=&a^{2}b^{3}\end{aligned}$